Tribocorrosive Aspects of Tungsten Carbide, Silicon Nitride, and Martensitic Steel under Fretting-like Conditions

نویسندگان

چکیده

Water-based lubrication faces the common challenge of component lifetime extension which is impaired by tribocorrosion due to material surface depassivation. However, such mechanisms in a pH-neutral and low-halide electrolyte require additional understanding. A ball-on-flat configuration study hard-phase materials low amplitude–high frequency sliding contact against martensitic chromium steel with pressures around 200 MPa presented. Under purified water, tungsten carbide-based metal matrix composite (MMC) NiCr binder silicon nitride-based ceramic (SiAlON) DIN/EN 1.4108 yielded coefficients friction above unity. Wear scar enlargement led fretting-like conditions adhesion becoming fundamental wear mechanism. tribocorrosion-induced depletion carbide nickel was determined for MMC. SiAlON suffered extreme under formation abrasive SiO2, while heat-treated 1.4125 showed lower wear, but also signs hydrogen embrittlement. Results from accompanying single-material corrosion experiments could not satisfactorily explain phenomena. Including galvanic interaction influence geometry, new model fretting proposed. It describes an expanding anodic belt located at inner-most crevice position otherwise cathodically polarized material. Low conductivity seen as key player this process, situation between two shown invert when water substituted wet organic phase.

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ژورنال

عنوان ژورنال: Lubricants

سال: 2023

ISSN: ['2075-4442']

DOI: https://doi.org/10.3390/lubricants11050195